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W Parker's Alicyclic Chemistry Vol. 4 PDF

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M. Fabre, and L. Giral, Tetrahedron Letters, 1974, 1439; see also M. Larcheveque. A. Debal, and T. Cuvigny, Bull. chim France, 1974,1710. G. Stork and J. F. Cohen, J. Amer. Chem. , 1974,%, 5270. 43 Three- and Four-membered Rings formed in preference to cyclopentanes. This has been adapted into a general synthesis of functionalized cyclobutanes, and is illustrated by the preparation of ( f)-grandis01 (Scheme 16). 226 Treatment of the tosylate (174) with methanolic potash gives either the cyclobutyl ether (175; X = OMe) or cyclohexenone (176), depending on the reaction times.

1974, 80, 82215,82216). V. F. Mironov, V. D. Sheludyakova, 0. M. Radkova, V. I. Andreev, and M. P. S. P. 3808247 (Chem. , 1974, 81, 25796). I. D. Kushina, 0. M. Nefedov, A. A. Ivashenko, S. F. Politanskii, V. U. Shevchuk, I. M. Gutor, and A. Y. Shteinschneider, Izvest. Akad. , Ser. , 1974, 728 (Chem. , 1974, 81, 12743); I. D. Kushina, S. F. Politanskii, V. U. Shevchuk, I. M. Gutor, A. A. Ivashenko, and 0. M. , p. 946 (Chern. , 1974, 81, 24623); 0. M. Nefedov and A. A. , p. 1651 (Chem. , 1974, 81, 104944).

Chim. , 1974, 57, 1876. Y. M. Sheikh, J. Leclercq, and C. S. Perkin I , 1974, 909. R. Mathias and P. Weyerstahl, Angew. Chem Internat. , 1974, 13, 132. K. Isagawa, Y. Kimura,and S. Kwon, J . Org. , 1974,39, 3171. M. Makosza and M. Ludwikow, Angew. Chem Internat. , 1974, 13,665. 126They noted that the carbenoid resulting from treatment of (64) with potassium t-butoxide in t-butyl alcohol differed in its selectivity of addition to olefins from that generated by photolysis of (65), the latter method giving a 'free carbene' and the former a 'carbenoid'.

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